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January 13, 20253 min readWhat Makes Urban Wildfire Smoke So ToxicWildfires burning in cities unleash a toxic, unpredictable combination of compounds into the airBy Allison Parshall edited by Dean VisserSmoke over destroyed homes in the aftermath of the Eaton Fire in Altadena, California, US, on Saturday, Jan. 11, 2025. Firefighters are making some progress on controlling the deadly blazes that have scorched Los Angeles, as the toll of destruction rises with entire neighborhoods reduced to ash. Kyle Grillot/Bloomberg via Getty ImagesFirefighters in southern California are battling the Palisades and Eaton Fires, which have killed at least 25 people, burning a cumulative 37,700 acres and at least 12,000 structures. The plumes of smoke are even visible from space.Residents of many fire-prone areasas well as those far downwindhave grown familiar with the orange, apocalyptic haze of wildfire smoke as these blazes have become more common because of climate change. Such smoke can contain an unpredictable cocktail of chemicals associated with heart and lung diseases and even cancer, which is the leading cause of death among firefighters. Heres what makes wildfire smoke so dangerous.No Ordinary PollutantOn supporting science journalismIf you're enjoying this article, consider supporting our award-winning journalism by subscribing. By purchasing a subscription you are helping to ensure the future of impactful stories about the discoveries and ideas shaping our world today.When trees, shrubbery and other organic matter burn, they release carbon dioxide, water, heatand, depending on the available fuel, various volatile compounds, gaseous pollutants and particulate matter. Those tiny particles, which become suspended in the air, can include soot (black carbon), metals, dust, and more. If theyre smaller than 2.5 microns in diameter, they can evade our bodys natural defenses when inhaled, penetrating deep into the lungs and triggering a wide variety of health problems.Such fine particulate matter is a common pollutant; it's also created by motor vehicles and industrial plants, for example. But the kind present in wildfire smoke might be even more dangerous. Researchers studying health outcomes in southern California concluded that exposure to particular matter smaller than 2.5 microns, called PM2.5, from wildfires was up to 10 times more harmful to human health compared with exposure to PM2.5 from other sources. The researchers estimated that wildfire-generated particulate matter was three to four times more toxicbut they dont yet know why.More Dangerous FuelAs humans develop ever more land, we grow the number of points of contact between human settlements and increasingly flammable forests. This makes it more likely that an errant, human-caused spark will ignite a blazeand that the resulting wildfire will consume homes, offices, cars and other human-made infrastructure, expanding the types and amounts of toxic compounds going up in the smoke. Paints, sealants, insulations, metals, and more can release many kinds of volatile organic compounds, gaseous pollutants and particulate matter.A 2023 study by researchers at the Environmental Protection Agency found that emission factors for some toxic compounds were more than 1,000 times higher in urban wildfires than in fires that burned in woodland areas.Unpredictable ChemistryIts surprisingly hard to predict what compounds someone is exposed to when they inhale wildfire smoke. Whats in the smoke depends on a few factors: what was burned (a ponderosa pine, for example, or a car), the temperature at which it burned (was it flaming or smoldering?) and how far and for how long the smoke has traveled. As the smoke ages, it is exposed to sunlight. This radiation can hit nitrogen oxides (NOx) and volatile organic compounds (VOCs), setting off a complex set of reactions that usually results in another secondary pollutant: ozone, the main component of smog, which can damage the lungs.And as smoke containing VOCs travels and settles over other cities, it can mix with even more local pollution in the form of NOxgiving it the opportunity to form a larger amount of ozone. Research also suggests that VOCs and particulate mattereach of which can be toxiccan combine to make their respective health risks even worse.[Read more about scientists flying planes through wildfire plumes to figure out whats in the smoke]Lingering HazardsEven after wildfire smoke clears, it often leaves behind some of its toxic components. In a study conducted in Colorado after the 2021 Marshall Fire, researchers found high levels of polycyclic aromatic hydrocarbons (PAHs), which have been linked to respiratory and developmental conditions, infertility and cancer, in ash in homes that had survived the fire, as well as VOCs in air samples. Other researchers exposed glass, cotton and a mechanical air filter to smoke in a lab and found that PAHs lingered above background levels for 40 days. Cleaning processes were between 48 and 71 percent effective.This lingering contamination can cause health problems, too. In the study following the Marshall Fire, many residents experienced itchy or watery eyes, headache, coughing and sneezing. This has led to some disputes between homeowners and insurers over what exactly constitutes damage from wildfire smoke.Some of the smoke has begun to clear around Los Angeles, much of it blown out to sea by the same Santa Ana winds that so disastrously fanned the flames in the first place. But the city is currently bracing for more high winds as the National Weather Service warns of the potential for a potential explosive fire growth in the next few days.
